ESR Facility - Department of Chemistry

  1. Macpherson, H.; Cornes, S.; Zhou, S.; Porfyrakis, K.; A porphyrin-centred fullerene tetramer containing an N@C60 substituent, Royal Society Open Science 2018, (doi: 10.1098/rsos.180338).
  2. Doyle, L.R.; Scott, D.J.; Hill, P.J.; Fraser, D.A.X.; Myers, W.K.; White, A.J.P.; Green, J.C.; Ashley, A.E.; Reversible coordination of N2 and H2 to a homoleptic S = 1/2 Fe(I) diphosphine complex in solution and the solid state, Chemical Science 2018, (doi: 10.1039/c8sc01841c).
  3. Evans, E.; Olivier, Y; Puttisong, Y; Myers, W.K.; Hele, T.J.H.; Menke, S.M.; Thomas,T.H.; Credgington, D.; Beljonne, D.; Friend, R.H.; Greenham, N.C.; Vibrationally Assisted Intersystem Crossing in Benchmark Thermally Activated Delayed Fluorescence Molecules, J. Phys. Chem. Lett. 2018, ASAP, (doi: 10.1021/acs.jpclett.8b01556).
  4. Slota, M.; Keerthi, A.; Myers, W.K.; Tretyakov, E.; Baumgarten, M.; Ardavan, A.; Sadeghi, H.; Lambert, C.J.; Narita, A.; Müllen, K.; Bogani, L.; Magnetic edge states and coherent manipulation of graphene nanoribbons, Nature 2018, 557, 691–695, (doi: 10.1038/s41586-018-0154-7).
  5. Liu, J.; Mrozek, J.; Myers, W.K.; Timco, G.A.; Winpenny, R.E.P.; Kintzel, B.; Plass, W.; Ardavan, A.; Electric field control of spins in molecular magnets, arXiv:1805.05256, 2018.
  6. Hu, Z.; Dong, B.W.; Liu, Z.; Liu, J.J.; Su, J.; Yu, C.; Xiong, J.; Shi, D.E.; Wang, Y.; Wang, B.W.; Ardavan, A.; Endohedral metallofullerene as molecular high spin qubit: diverse Rabi cycles in Gd2@ C79N, Journal of the American Chemical Society 2018, 140(3),1123-1130, (doi: 10.1021/jacs.7b12170).
  7. Ebrahimi, K.H.; Silveira, C.; Todorovic S.; Evidence for the synthesis of an unusual high spin (S = 7/2) [Cu–3Fe–4S] cluster in the radical-SAM enzyme RSAD2 (viperin), Chem. Commun. 2018, (doi: 10.1039/C8CC03565B).
  8. Ebrahimi, K.H.; A unifying view of the broad-spectrum antiviral activity of RSAD2 (viperin) based on its radical-SAM chemistry, Metallomics 2018, 10(4), 539-552, (doi: 10.1039/C7MT00341B).
  9. Dijkman, P.M.; Castell, O.K.; Goddard, A.D.; Munoz-Garcia, J.C.; de Graaf, C.; Wallace, M.I.; Watts, A.; Dynamic tuneable G protein-coupled receptor monomer-dimer populations, Nature Communications 2018, 9, 1710, (doi:10.1038/s41467-018-03727-6).
  10. Beaton, S.E.; Evans, R.M.; Finney, A.J.; Lamont, C.M.; Armstrong, F.A.; Sargent, F.; Carr, S.B.; The structure of hydrogenase-2 from Escherichia coli: implications for H2-driven proton pumping, Biochemical Journal 2018, 475(7), 1353-1370, (doi: 10.1042/BCJ20180053).
  11. Bowen, A.M.; Johnson, E.O.D.; Mercuri, F; Hoskins, N.J.; Qiao, R; McCullagh, J.S.O., Lovett, J.E., Bell, S.G.; Zhou, W.; Timmel, C.R.; Wong, L.L.; Harmer, J.R.; A Structural Model of a P450-Ferredoxin Complex from Orientation-Selective Double Electron–Electron Resonance Spectroscopy, J. Am. Chem. Soc. 2018, 140(7), 2514–2527, (doi: 10.1021/jacs.7b11056).
  12. Honarmand Ebrahimi, K.; Carr, S.B.; McCullagh, J.; Wickens, J.; Rees, N.H.; Cantley, J.; Armstrong, F.A.; The radical-SAM enzyme Viperin catalyzes reductive addition of a 5'-deoxyadenosyl radical to UDP-glucose in vitro, FEBS Letters 2017, 591, 2394–2405, (doi:10.1002/1873-3468.12769).
  13. Harding, R.T.; Zhou, S.; Zhou, J.; Lindvall, T.; Myers, W.K.; Ardavan, A.; Briggs, G.A.D.; Porfyrakis, K.; Laird, E.A.; Spin Resonance Clock Transition of the Endohedral Fullerene 15N@C60, Physical Review Letters 2017, 119(14):140801, (doi: 10.1103/physrevlett.119.140801).
  14. Duan, H.; Dong, J.; Gu, X.; Peng, Y.-K.; Chen, W.; Issariyakul, T.; Myers, W.K.; Li, M.-J.; Yi, N.; Kilpatrick, A.; Wang, Y.; Zheng, X.; Ji, S.; Wang, Q.; Feng, J.; Chen, D.; Li, Y.; Buffet, J.-C.; Liu, H.-C.; Tsang, S.C.; and O'Hare, D.; Hydrodeoxygenation of Water-Insoluble Bio-Oil to Alkanes using a Highly Dispersed Pd-Mo Catalyst, Nature Communications, 2017, 8 (1), 591, (doi: 10.1038/s41467-017-00596-3).
  15. Carrington, B; Myers, W.K.; Horanyi, P.; Calmiano, M.; Lawson, A.D.G.; Natural Conformational Sampling of Human TNFα Visualized by Double Electron-Electron Resonance, Biophysical Journal, 2017, 113(2), 371–380, (doi: 10.1016/j.bpj.2017.06.007).
  16. Liou, S.-H.; Myers, W.K.; Oswald, J.D.; Britt, R.D.; Goodin, D.B.; Putidaredoxin Binds to the Same Site on Cytochrome P450cam in the Open and Closed Conformation, Biochemistry, 2017, (doi: 10.1021/acs.biochem.7b00564).
  17. Harding, R.T.; Zhou, S.; Zhou, J.; Lindvall, T.; Myers, W.K.; Ardavan, A.; Briggs, G.A.D.; Porfyrakis, K.; Laird, E.A.; The spin resonance clock transition of the endohedral fullerene 15N@C60, arXiv, 2017, 1705.04817v1.
  18. Foskolou, I.P.; Jorgensen, C.; Leszczynska, K.B.; Olcina, M.M.; Tarhonskaya, H.; Haisma, B.;  D’Angiolella, V.; Myers, W.K.; Domene, C.; Flashman, E.; Hammond, E.M., Ribonucleotide Reductase Requires Subunit Switching in Hypoxia to Maintain DNA Replication, Molecular Cell, 2017, 66, 2, pp 206-220 (doi: 10.1016/j.molcel.2017.03.005).
  19. Richert, S.; Limburg, B.; Anderson, H. L.; Timmel, C. R.; On the Influence of the Bridge on Triplet State Delocalization in Linear Porphyrin Oligomers, J. Am. Chem. Soc., 2017, 139 (34), pp 12003–12008 (doi: 10.1021/jacs.7b06518).
  20. Richert, S.; Bullard, G.; Rawson, J.; Angiolillo, P.J.; Therien, M.J.; Timmel, C.R.; On the Importance of Electronic Symmetry for Triplet State Delocalization,  J. Am. Chem. Soc., 2017, 139 (15), pp 5301–5304 (doi: 10.1021/jacs.7b01204).
  21. Richert, S.; Cremers, J.; Kuprov, I.; Peeks, M.D.; Anderson, H.L., Timmel, C.R.; Constructive quantum interference in a bis-copper six-porphyrin nanoring, Nature Comm., 2017, 8, 14842 (doi: 10.1038/ncomms14842).
  22. Richert, S.; Kuprov, I.; Peeks, M.D.; Suturina, E.A.; Cremers, J.; Anderson, H.L., Timmel, C.R.; Quantifying the exchange coupling in linear copper porphyrin oligomers, Phys. Chem. Chem. Phys., 2017, 19, 16057-16061, (doi: 10.1039/C7CP01787A).
  23. Richert, S.; Tait, C.E.; Timmel, C.R.; Delocalisation of photoexcited triplet states probed by transient EPR and hyperfine spectroscopy, Journal of Magnetic Resonance, 2017, 280, pp 103-116, (doi: 10.1016/j.jmr.2017.01.005).
  24. Hetzke, T.; Bowen, A.M.; Prisner, T.F.; ELDOR-detected NMR at Q-Band, App. Magn. Res., 2017, (doi: 10.1007/s00723-017-0927-4).
  25. Waters, J.B.; Everitt, T.A.; Myers, W.K.; Goicoechea, J.M.; N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P–P bond and its subsequent reactivity, Chem. Sci., 2016, 7, 6981-6987, (doi:10.1039/C6SC02343F).
  26. Hill, P.J.; Doyle, L.R.; Crawford, A.D.; Myers, W.K.; Ashley, A.E.; Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex, J. Am. Chem. Soc., 2016, 138 (41), 13521–13524, (doi:10.1021/jacs.6b08802).
  27. Baum, R.R.; Myers, W.K.; Greer, S. M.; Breece, R.M.; Tierney, D.L.; EPR of Scorpionates The Original CoII Heteroscorpionates Revisited: On the EPR of Pseudotetrahedral CoII, Eur. J. Inorg. Chem., 2016, 2641–2647, (doi:10.1002/ejic.201501356).
  28. Liu, J.; Goddard, P.A.; Singleton, J.; Brambleby, J.; Foronda, F.; Möller, J.S.; Kohama, Y.; Ghannadzadeh, S.; Ardavan, A.; Blundell, S.J.; Lancaster, T.; Xiao, F.; Williams, R.C.; Pratt, F.L.; Baker, P.J.; Wierschem, F.; Lapidus, S.H.; Stone, K.H.; Stephens, P.W.; Bendix, J; Woods, T.J.; Carreiro, K.E.; Tran, H.E.; Villa, C.J.; Manson, J.L.; Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine), Inorg. Chem., 2016, 55 (7), 3515–3529, (doi:10.1021/acs.inorgchem.5b02991).
  29. Kattnig, D.R.; Evans, E.W.; Déjean, V.; Dodson, C.A.; Wallace, M.I.; Mackenzie, S.R.; Timmel, C.R.; Hore, P.J.; Chemical amplification of magnetic field effects relevant to avian magnetoreception, Nature Chemistry, 2016, 8, 384–391, (doi:10.1038/nchem.2447).
  30. Evans, E.W.; Kattnig, D.R.; Henbest, K.B.; Hore, P.J.; Mackenzie, S.R.; Sub-millitesla magnetic field effects on the recombination reaction of flavin and ascorbic acid radicals, The Journal of Chemical Physics, 2016, 145, 085101, (doi:10.1063/1.4961266).
  31. Bowen, A.M., Jones, M.W., Lovett, J.E., Gaule, T.G., McPherson, M.J., Dilworth, J.R., Timmel, C.R., Harmer, J.R., Exploiting orientation-selective DEER: determining molecular structure in systems containing Cu(II) centres, Phys. Chem. Chem. Phys., 2016, 18, 5981-5994, (doi:10.1039/C5CP06096F).
  32. Cremers, J.; Richert, S.; Kondratuk, D.V.; Claridge, T.D.W.; Timmel, C.R.; Anderson, H.L.; Nanorings with copper(II) and zinc(II) centers: forcing copper porphyrins to bind axial ligands in heterometallated oligomers, Chem. Sci., 2016, 7, 6961-6968, (doi:10.1039/C6SC01809B).
  33. Tait, C.E.; Neuhaus, P.; Peeks, M.D.; Anderson, H.L.; Timmel, C.R.; Excitation wavelength-dependent EPR study on the influence of the conformation of multiporphyrin arrays on triplet state delocalization, Phys. Chem. Chem. Phys., 2016, 18, 5275-5280, (doi:10.1039/C5CP07424J).
  34. Richert, S.; Peeks, M.D.; Tait, C.E.; Anderson, H.L.; Timmel, C.R.; Photogenerated triplet states in supramolecular porphyrin ladder assemblies: an EPR study, Phys. Chem. Chem. Phys., 2016, 18, 24171-24175, (doi:10.1039/C6CP04444A).
  35. Richert, S.; Cremers, J.; Anderson, H.L.; Timmel, C.R.; Exploring template-bound dinuclear copper porphyrin nanorings by EPR spectroscopy, Chem. Sci., 2016, 7, 6952-6960, (doi:10.1039/C6SC01810F).
  36. Bolivar, J.H., Muñoz-García, J.C., Castro-Dopico, J., Dijkman, P.M.; Stansfeld, P.J.; Watts, A.; Interaction of lipids with the neurotensin receptor 1, Biochimica et Biophysica Acta (BBA) - Biomembranes, 2016, 1858, 6, 1278–1287, (doi:10.1016/j.bbamem.2016.02.032).
  37. Harmer, J.R., Hyperfine Spectroscopy – ENDOR, eMagRes, 2016, 5, 4, (doi:10.1002/9780470034590.emrstm1515).
  38. Fernandez, A.; Ferrando-Soria, J.; Pineda, E.M.; Tuna, F.; Vitorica-Yrezabal, I.J.; Knappke, C.; Ujma, J.; Muryn, C.A.; Timco, G.A.; Barran, P.E.; Ardavan, A.; Winpennya, R.E.P., Making hybrid [n]-rotaxanes as supramolecular arrays of molecular electron spin qubits, Nat Commun. 2016, 7, 10240, (doi:10.1038/ncomms10240).
  39. Kattnig, D.R.; Solov'yov, I.A.; Hore, P.J.; Electron spin relaxation in cryptochrome-based magnetoreception, Phys. Chem. Chem. Phys., 2016, 18, 12443-12456, (doi:10.1039/C5CP06731F).
  40. Schwarze, S.; Schneider, N.-L.; Reichl, T.; Dreyer, D.; Lefeldt, N.; Engels, S.; Baker, N.; Hore, P.J.; Mouritsen, N.; Weak Broadband Electromagnetic Fields are More Disruptive to Magnetic Compass Orientation in a Night-Migratory Songbird (Erithacus rubecula) than Strong Narrow-Band Fields Front Behav Neurosci., 2016, 10: 55, (doi:10.3389/fnbeh.2016.00055).
  41. Hiscock, H.G.; Kattnig, D.R.; Manolopoulos, D.E.; Hore, P.J.; Floquet theory of radical pairs in radiofrequency magnetic fields, The Journal of Chemical Physics, 2016, 145, 124117, (doi: 10.1063/1.4963793).
  42. Hore, P.J.; Mouritsen, H.; The Radical-Pair Mechanism of Magnetoreception, Annual Review of Biophysics, 2016, 45, 299-344, (doi:10.1146/annurev-biophys-032116-094545).
  43. Zhou, S.; Yamamoto, M.; Briggs, G.A.D.; Imahori, H.; Porphyrakis, K.; Probing the Dipolar Coupling in a Heterspin Endohedral Fullerene-Phthalocyanine Dyad, J. Am. Chem. Soc., 2016, 138, 1313-1319, (doi: 10.1021/jacs.5b11641).
  44. Baumann, S.; Paul, W.; Choi, T.; Lutz, C. P.; Ardavan, A.; Heinrich, A. J.; Electron paramagnetic resonance of individual atoms on a surface, Science 2015, 350, 6259, 417-420, (doi: 10.1126/science.aac8703).
  45. Zhou, S.; Rašovic, I.; Briggs, G. A. D.; Porfyrakis, K.; Synthesis of the first completely spin-compatible N@C60 cyclopropane derivatives by carefully tuning the DBU base catalyst, Chem. Commun., 2015, 51, 7096-7099, (doi: 10.1039/C5CC01459J).
  46. Spielberg, E. T.; Gilb, A.; Plaul, D.; Geibig, D.; Hornig, D.; Schuch, D.; Buchholz, A.; Ardavan, A.; Plass, W.; A Spin-Frustrated Trinuclear Copper Complex Based on Triaminoguanidine with an Energetically Well-Separated Degenerate Ground State, Inorg. Chem., 2015, 54 (7), 3432–3438, (doi: 10.1021/ic503095t).
  47. Blackburn, O. A.; Chilton, N. F.; Keller, K.; Tait, C. E.; Myers, W. K.; McInnes, E. J. L.; Kenwright, A. M.; Beer, P. D.; Timmel, C. R.; Faulkner, S.; Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb·DTMA]3+ in Aqueous Solution, Angew. Chem., 2015, 127, 1 – 5, (doi: 10.1002/anie.201503421).
  48. Brambleby, J. ; Goddard, P. A.; Johnson, R. D.; Liu, J.; Kaminski, D.; Ardavan, A.; Steele, A. J.; Blundell, S. J.; Lancaster, T.; Manuel, P.; Baker, P. J.; Singleton, J.; Schwalbe, S. G.; Spurgeon, P. M.; Tran, H. E.; Peterson, P. K.; Corbey, J. F.; Manson, J. L.; Magnetic ground state of the two isostructual polymeric quantum magnets [Cu(HF2)(pyrazine)2]SbF6 and [Co(HF2)(pyrazine)2]SbF6 investigated with neutron powder diffraction, Phys. Rev. B 2015, 92, 134406, (doi: 10.1103/PhysRevB.92.134406).
  49. Binding, S.C.; Green, J.C.; Myers, W.K.; O’Hare,D.; Synthesis, Structure, and Bonding for Bis(permethylpentalene)diiron, Inorg. Chem. 2015, (doi: 10.1021/acs.inorgchem.5b02254).
  50. Fowler, P. W.; Orwick-Rydmark, M.; Radestock, S; Solcan, N.; Dijkman, P. M.; Lyons, J. A.; Kwok, J; Caffrey, M; Watts, A; Forrest, L. R.; Newstead, S.; Gating Topology of the Proton-Coupled Oligopeptide Symporters, Structure, 2015, 23, 2, 290–301 (doi: 10.1016/j.str.2014.12.012).
  51. Miles Z.D.; Myers, W.K.; Kincannon, W.M.; Britt, R.D.; Bandarian, V.; Biochemical and Spectroscopic Studies of Epoxyqueuosine Reductase: A Novel Iron-Sulfur Cluster- and Cobalamin-Containing Protein Involved in the Biosynthesis of Queuosine, Biochemistry 2015, 54(31), 4927-4935, (doi: 10.1021/acs.biochem.5b00335).
  52. Murphy, B. J.; Hidalgo, R.; Roessler, M. M.; Evans, R. M.; Ash, P. A.; Myers, W. K.; Vincent, K. A.; Armstrong, F. A.; Discovery of Dark pH-Dependent H+ Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate, J. Am. Chem. Soc., 2015, 137, 26, 8484–8489, (doi: 10.1021/jacs.5b03182).
  53. Zhou, S.; Rašovic, I.; Briggs, G. A. D.; Porfyrakis, K. Synthesis of the first completely spin-compatible N@C60 cyclopropane derivatives by carefully tuning the DBU base catalyst, Chem. Commun., 2015, 51, 7096-7099 (doi: 10.1039/C5CC01459J).
  54. Chang, Y.G.; Cohen, S.E.; Phong, C.; Myers, W.K.; Kim, Y.I.; Tseng, R.; Lin, J.; Zhang, L.; Boyd, J.S.; Lee, Y.; et al.; Circadian rhythms. A protein fold switch joins the circadian oscillator to clock output in cyanobacteria. Science 2015, 349(6245), 324-328 (doi: 10.1126/science.1260031).
  55. Tait, C.E.; Neuhaus, P.; Peeks, M.D.; Anderson, H.L.; Timmel, C. R. Transient EPR reveals triplet state delocalization in a series of cyclic and linear p-conjugated porphyrin oligomers, J. Am. Chem. Soc., 2015, 137, 25, 8284–8293, (doi: 10.1021/jacs.5b04511).
  56. Maeda, K.; Storey, J. G.; Liddell, P. A.; Gust, D.; Hore, P. J.; Wedge, C. J.; Timmel, C. R. Probing a chemical compass: novel variants of low-frequency reaction yield detected magnetic resonance, Phys. Chem. Chem. Phys., 2015, 17, 3550-3559, (doi: 10.1039/C4CP04095C).
  57. Sun, Y.; Borbat, P.P.; Grigoryants, V.M.; Myers, W.K.; Freed, J.H.; Scholes, C.P.; Pulse dipolar ESR of doubly labeled mini TAR DNA and its annealing to mini TAR RNA, Biophysical Journal 2015, 108(4), 893-902, (doi: 10.1016/j.bpj.2014.12.028).
  58. Dodson, C. A.; Wedge, C. J.; Murakami, M.; Maeda, K.; Wallace M. I.; Hore, P. J. Fluorescence-detected magnetic field effects on radical pair reactions from femtolitre volumes, Chem. Commun., 2015, 51, 8023-8026, (doi: 10.1039/C5CC01099C).
  59. Tait, C. E.; Neuhaus, P.; Anderson, H. L.; Timmel, C. R.; Carbonera, D.; Di Valentin, M. HYSCORE on Photoexcited Triplet States, Appl. Magn. Reson. 2015 46:389–409, (doi: 10.1007/s00723-014-0624-5).
  60. Bachmeier, A.; Esselborn, J.; Hexter, S. V.; Krämer, T.; Klein, K.; Happe, T.; McGrady, J. E.; Myers, W. K.; Armstrong, F. A. How Formaldehyde Inhibits Hydrogen Evolution by [FeFe]-Hydrogenases: Determination by 13C ENDOR of Direct Fe–C Coordination and Order of Electron and Proton Transfers,  J. Am. Chem. Soc. 2015, 137, 16, 5381–5389, (doi: 10.1021/ja513074m).
  61. Tait, C.E.; Neuhaus, P.; Anderson, H.L.; Timmel, C. R. Triplet State Delocalization in a Conjugated Porphyrin Dimer Probed by Transient Electron Paramagnetic Resonance Techniques, J. Am. Chem. Soc., 2015, 137, 20, 6670–6679, (doi: 10.1021/jacs.5b03249).
  62. Yong, S.C.; Roversi, P.; Lillington, J.; Rodriguez, F.; Krehenbrink, M.; Zeldin, O.B.; Garman, E.F.; Lea, S.M.; Berks, B.C. A complex iron-calcium cofactor catalyzing phosphotransfer chemistry, Science, 2014, 345, 6201, 1170-1173, (doi: 10.1126/science.1254237).
  63. Grabarczyk, D. B.; Ash, P. A.; Vincent, V. Infrared Spectroscopy Provides Insight into the Role of Dioxygen in the Nitrosylation Pathway of a [2Fe2S] Cluster Iron-Sulfur Protein, J. Am. Chem. Soc. 2014, 136, 11236-11239 (doi: 10.1021/ja505291j).
  64. Kaminski, D.; Webber, A. L.; Wedge, C. J.; Liu, J.; Timco, G.A.; Vitorica-Yrezabal, I. J.; McInnes, E. J. L.; Winpenny, R. E. P.; Ardavan, A. Quantum spin coherence in halogen-modified Cr7Ni molecular nanomagnets, Phys. Rev. B, 2014, 90, 184419, (doi: 10.1103/PhysRevB.90.184419).
  65. Rodriguez, F.; Lillington, J.; Johnson, S.; Timmel, C.R.; Lea, S.M.; Berks, B.C. Crystal Structure of the Bacillus subtilis Phosphodiesterase PhoD Reveals an Iron and Calcium-containing Active Site, J. BIOL. CHEM., 2014, 289, 45, 30889-30899, ().
  66. Myers, W.K.; Stich, T.A.; Suess, D.L.; Kuchenreuther, J.M.; Swartz, J.R.; Britt, R.D.; The cyanide ligands of [FeFe] hydrogenase: pulse EPR studies of (13)C and (15)N-labeled H-cluster. J. Am. Chem. Soc. 2014, 136(35), 12237-12240 (doi: 10.1021/ja507046w).
  67. Lo, C. C.; Simmons, S.; Lo Nardo, R.; Weis, C. D.; Tyryshkin, A. M.; Meijer,  J. ; Rogalla, D.; Lyon, S. A.; Bokor, J.; Schenkel, T.; Morton, J. J. L. Stark shift and field ionization of arsenic donors in 28Si-silicon-on-insulator structures, Appl. Phys. Lett. 2014, 104, 193502 (doi: 10.1063/1.4876175).
  68. Moro, F.; Kaminski, D.; Tuna, F.; Whitehead, G. F. S.; Timco, G. A.; Collison D.; Winpenny, R. E. P.; Ardavan, A.; McInnes, E. J. L. Coherent electron spin manipulation in a dilute oriented ensemble of molecular nanomagnets: pulsed EPR on doped single crystals, Chem. Commun. 2014, 50, 91-93 (doi: 10.1039/C3CC46326E).
  69. Stich, T.A.; Myers, W.K.; Britt, R.D.; Paramagnetic intermediates generated by radical S-adenosylmethionine (SAM) enzymes, Accounts of Chemical Research 2014, 47(8), 2235-2243 (doi:10.1021/ar400235n).
  70. Di Valentin, M.; Tait, C. E.; Salvadori, E.; Orian, L.; Polimeno, A.; Carbonera, D. Evidence for water-mediated triplet–triplet energy transfer in the photoprotective site of the peridinin–chlorophyll a–protein, BBA-Bioenergetics 2014, 1837 (1), 85–97 (doi:10.1016/j.bbabio.2013.07.005).
  71. Kuchenreuther, J.M.; Myers, W.K.; Suess, D.L.; Stich, T.A.; Pelmenschikov, V.; Shiigi, S.A.; Cramer, S.P.; Swartz, J.R.; Britt, R.D.; George, S.J.; The HydG enzyme generates an Fe(CO)2(CN) synthon in assembly of the FeFe hydrogenase H-cluster, Science 2014, 343(6169):424-427 (doi:10.1126/science.1246572).
  72. Espinoza-Quintero, G.; Duckworth, J. C. A.; Myers, W. K.; McGrady, J. E.; Goicoechea, J. M. Synthesis and characterization of [Ru@Ge12]3–: an endohedral 3-connected cluster, J. Am. Chem. Soc. 2014, 136 (4), 1210–1213 (doi:10.1021/ja411280v).
  73. Bowen, A. M.; Tait, C. E.; Timmel, C. R.; Harmer, J. R. Orientation-Selective DEER Using Rigid Spin Labels, Cofactors, Metals, and Clusters, Struct. Bond. 2014, (doi:10.1007/430_2013_115).
  74. Kuchenreuther, J.M.; Myers, W.K.; Stich, T.A.; George, S.J.; NejatyJahromy, Y.; Swartz, J.R.; Britt, R.D.; A Radical Intermediate in Tyrosine Scission to the CO and CN− Ligands of [FeFe] Hydrogenase, Science 2013, 342(6157):472-475 (doi:10.1126/science.1241859).
  75. Myers, W.K.; Xu, X.; Li, C.; Lagerstedt, J.O.; Budamagunta, M.S.; Voss, J.C.; Britt, R.D.; Ames, J.B.; Double electron-electron resonance probes Ca²⁺-induced conformational changes and dimerization of recoverin, Biochemistry 2013, 52(34), 5800-5808 (doi:10.1021/bi400538w).
  76. Myers, W.K.; Lee, Y.T.; Britt, R.D.; Goodin, D.B.; The conformation of P450cam in complex with putidaredoxin is dependent on oxidation state., J. Am. Chem. Soc. 2013, 135(32), 11732-11735, (doi:10.1021/ja405751z).
  77. Maeda, K.; Liddell, P.; Gust, D.; Hore, P. J. Spin-selective recombination reactions of radical pairs: Experimental test of validity of reaction operators, J. Chem. Phys. 2013, 139, 234309 (doi:10.1063/1.4844355).
  78. Filidou, V.; Mamone, S.; Simmons, S.; Karlen, S. D.; Anderson, H. L.; Kay, C. W. M.; Bagno, A. Rastrelli, F.; Murata, Y.; Komatsu, K.; Lei, X.; Li, Y.; Turro, N. J.; Levitt, M. H.; Morton, J. J. L. Probing the C60 triplet state coupling to nuclear spins inside and out, Phil. Trans. R. Soc. A 2013, 371, 20120475 (doi:0.1098/rsta.2012.0475).
  79. Evans, E. W.; Dodson, C. A.; Maeda, K.; Biskup, T.; Wedge, C. J.; Timmel, C. R. Magnetic field effects in flavoproteins and related systems, Interface Focus 2013, 3, 20130037 (doi: 10.1098/rsfs.2013.0037).
  80. Lovett, J. E.; Abbott, R. J. M.; Roversi, P.; Johnson, S.; Caesar, J. J. E.; Doria, M.; Jeschke, G; Timmel, C. R.; Lea, S. M. Investigating the structure of the factor B vWF-A domain/CD55 protein–protein complex using DEER spectroscopy: successes and pitfalls, Molecular Physics 2013, 111 (18–19), 2865–2872 (doi:10.1080/00268976.2013.827754).
  81. Lodge, M. T. J. H.; Cullen, P.; Rees, N. H.; Spencer, N.; Maeda, K.; Harmer, J. R.; Jones, M. O.; Edwards, P. P. Multielement NMR Studies of the Liquid-Liquid Phase Separation and the Metal-to-Nonmetal Transition in Fluid Lithium- and Sodium-Ammonia Solutions, J. Phys. Chem. B 2013, 117, 13322-13334 (doi:10.1021/jp404023j).
  82. Plant, S. R.; Jevric, M.; Morton, J. J. L.; Ardavan, A.; Khlobystov, A. N.; Briggs, G. A. D.; Porfyrakis, K. A two-step approach to the synthesis of N@C60 fullerene dimers for molecular qubits, Chem. Sci. 2013, 4, 2971-2975 (doi:10.1039/C3SC50395J).
  83. Krämer, T.; Duckworth, J. C. A.; Ingram, M. D.; Zhou, B.; McGrady, J. E.; Goicoechea, J. M. Structural trends in ten-vertex endohedral clusters, M@E10 and the synthesis of a new member of the family, [Fe@Sn10]3−, Dalton Trans. 2013, 42, 12120-12129 (doi:10.1039/C3DT50643F).
  84. Rodriguez, F.; Rouse, S. L.; Tait, C. E.; Harmer, J.; De Riso, A.; Timmel, C. R.; Sansom, M. S. P.; Berks, B. C.; Schnell, J. R. Structural model for the protein-translocating element of the twin-arginine transport system, PNAS 2013, 110 (12), E1092-E1101 (doi:10.1073/pnas.1219486110).
  85. Laidlaw, W. M.; Denning, R. G.; Green, J. C.; Boyd, J.; Harmer, J.; Thompson, A. L. 140 H/D Isotopomers Identified by Long-Range NMR Hyperfine Shifts in Ruthenium(III) Ammine Complexes. Hyperconjugation in Ru–NH3 Bonding, Inorg. Chem. 2013, 52 (12), 7280–7294 (doi:10.1021/ic400903a).
  86. Harmer, J. DEER of Metalloproteins, Encyclopedia of Biophysics 2013, Roberts, G.C.K. (ed.), (doi:10.1007/978-3-642-16712-6).
  87. Evans, R. M.; Parkin, A.; Roessler, M. M.; Murphy, B. J.; Adamson, H.; Lukey, M. J.; Sargent, F.; Volbeda, A.; Fontecilla-Camps, J.; Armstrong, A. A. Principles of Sustained Enzymatic Hydrogen Oxidation in the Presence of Oxygen – The Crucial Influence of High Potential Fe–S Clusters in the Electron Relay of [NiFe]-Hydrogenases, J. Am. Chem. Soc. 2013, 135 (7), 2694–2707 (doi:10.1021/ja311055d).
  88. Laidlaw, W. M.; Thompson, A. L.; Denning, R. G. Solvent and metal dependent 1H NMR hyperfine shifts in paramagnetic pentaamminemetal cyanide-bridged mixed-valence complexes, Dalton Trans. 2013, 42, 4695-4703 (doi:10.1039/C3DT32978J).
  89. Wedge, C. J.; Timco, G. A.; Spielberg, E. T.; George, R. E.; Tuna, F.; Rigby, S.; McInnes, E. J. L.; Winpenny, R. E. P.; Blundell, S. J.; Ardavan, A. Chemical engineering of molecular qubits, Phys. Rev. Lett. 2012, 108, Art. No. 107204 (doi:10.1103/PhysRevLett.108.107204).
  90. Maeda, K.; Lodge, M. T. J.; Harmer, J.; Freed, J. H.; Edwards, P. P. Electron Tunneling in Lithium-Ammonia Solutions Probed by Frequency-Dependent Electron Spin Relaxation Studies, J. Am. Chem. Soc. 2012, 134, 9209-9218 (doi:10.1021/ja212015b).
  91.  Volbeda, A.; Amara, P.; Darnault, C.; Mouesca, J.-M.; Parkin, A.; Roessler, M. M.; Armstrong, F. A.; Fontecilla-Camps, J. C. X-ray crystallographic and computational studies of the o2-tolerant [nife]-hydrogenase 1 from escherichia coli, Proceedings of the National Academy of Sciences of the United States of America 2012, 109, 5305-5310 (doi: 10.1073/pnas.1119806109).
  92.  Orwick, M.; Judge, P.; Procek, J.; Lindholm, L.; Graziadei, A.; Engel, A.; Grobner, G.; Watts, A. Detergent-free formation and physico-chemical characterization of nanosized lipid-polymer complexes - lipodisq, Angewante Chemie 2012, 124, 1-6 (doi: anie.201201355).
  93.  Maeda, K.; Robinson, A. J.; Henbest, K. B.; Hogben, H. J.; Biskup, T.; Ahmad, M.; Schleicher, E.; Weber, S.; Timmel, C. R.; Hore, P. J. Magnetically sensitive light-induced reactions in cryptochrome are consistent with its proposed role as a magnetoreceptor, Proceedings of the National Academy of Sciences of the United States of America 2012, 109, 4774-4779 (doi: 10.1073/pnas.111895910).
  94.  Lukey, M. J.; Roessler, M. M.; Parkin, A.; Evans, R. M.; Davies, R. A.; Lenz, O.; Friedrich, B.; Sargent, F.; Armstrong, F. A. Oxygen-tolerant [nife]-hydrogenases: The individual and collective importance of supernumerary cysteines at the proximal fe-s cluster, Journal of the American Chemical Society 2012, 133, 16881-16892 (doi: 10.1021/ja205393w).
  95.  Knee, G. C.; Simmons, S.; Gauger, E. M.; Morton, J. J. L.; Riemann, H.; Abrosimov, N. V.; Becker, P.; Pohl, H.-J.; Itoh, K. M.; Thewalt, M. L. W.; Briggs, G. A. D.; Benjamin, S. C. Violation of a leggett-garg inequality with ideal non-invasive measurements, Nature Communications 2012, 3 (doi:60610.1038/ncomms1614).
  96.  Filidou, V.; Simmons, S.; Karlen, S. D.; Giustino, F.; Anderson, H.; Morton, J. Ultrafast entangling gates between nuclear spins using photo-excited triplet states, 2012, arXiv:1201.4805 (doi: NA).
  97.  Farrington, B. J.; Jevric, M.; Rance, G. A.; Ardavan, A.; Khlobystov, A. N.; Briggs, G. A. D.; Porfyrakis, K. Chemistry at the nanoscale: Synthesis of an n@c60-n@c60 endohedral fullerene dimer, Angewandte Chemie International Edition 2012, 51, 3587-3590 (doi: 10.1002/anie.201107490).
  98.  Bell, S. G.; Yang, W.; Yorke, J. A.; Zhou, W. H.; Wang, H.; Harmer, J.; Copley, R.; Zhang, A. L.; Zhou, R. M.; Bartlam, M.; Rao, Z. H.; Wong, L. L. Structure and function of cyp108d1 from novosphingobium aromaticivorans dsm12444: An aromatic hydrocarbon-binding p450 enzyme, Acta Crystallogr. Sect. D-Biol. Crystallogr. 2012, 68, 277-291 (doi: 10.1107/s090744491200145x).
  99.  Bell, S. G.; Xu, F.; Johnson, E. O. D.; Forward, I. M.; Bartlam, M.; Rao, Z.; Wong, L.-L. Protein recognition in ferredoxin-p450 electron transfer in the class i cyp199a2 system from rhodopseudomonas palustris, Journal of Biological Inorganic Chemistry 2012, 15, 315-328 (doi: 10.1007/s00775-009-0604-7).
  100.  Akhtar, W.; Filidou, V.; Sekiguchi, T.; Kawakami, E.; Itahashi, T.; Vlasenko, L.; Morton, J. J. L.; Itoh, K. M. Coherent storage of photoexcited triplet states using si-29 nuclear spins in silicon, Phys. Rev. Lett. 2012, 108, Article Number: 097601 (doi: 09760110.1103/PhysRevLett.108.097601).
  101.  Abdalla, J. A. B.; Bowen, A. M.; Bell, S. G.; Wong , L. L.; Timmel, C. R.; Harmer, J. Characterisation of the paramagnetic [2Fe–2S]+ centre in palustrisredoxin-b (puxb) from rhodopseudomonas palustris cga009: G-matrix determination and spin coupling analysis, Physical Chemistry Chemical Physics 2012, Advance Article (doi: 10.1039/C2CP24112A).
  102.  Wong, L.-L. P450bm3 on steroids: The swiss army knife p450 enzyme just gets better, Chembiochem 2011, 12, 2537-2539 (doi: 10.1002/cbic.201100606).
  103.  Simmons, S.; Brown, R. M.; Riemann, H.; Abrosimov, N. V.; Becker, P.; Pohl, H. J.; Thewalt, M. L. W.; Itoh, K. M.; Morton, J. J. L. Entanglement in a solid-state spin ensemble, Nature 2011, 470, 69-72 (doi: 10.1038/nature09696).
  104.  Ramachandran, P. L.; Lovett, J. E.; Carl, P. J.; Cammarata, M.; Lee, J. H.; Jung, Y. O.; Ihee, H.; Timmel, C. R.; van Thor, J. J. The short-lived signaling state of the photoactive yellow protein photoreceptor revealed by combined structural probes, Journal of the American Chemical Society 2011, 133, 9395-9404 (doi: 10.1021/ja200617t).
  105.  Parkin, A.; Bowman, L.; Roessler, M. M.; Davies, R. A.; Palmer, T.; Armstrong, F. A.; Sargent, F. How salmonella oxidises h-2 under aerobic conditions, FEBS Letters 2011, 586, 536-544 (doi: 10.1016/j.febslet.2011.07.044).
  106.  Maeda, K.; Wedge, C. J.; Storey, J. G.; Henbest, K. B.; Liddell, P. A.; Kodis, G.; Gust, D.; Hore, P. J.; Timmel, C. R. Spin-selective recombination kinetics of a model chemical magnetoreceptor, Chemical Communications 2011, 47, 6563-6565 (doi: 10.1039/c1cc11625h).
  107.  Lo, C. C.; Lang, V.; George, R. E.; Morton, J. J. L.; Tyryshkin, A. M.; Lyon, S. A.; Bokor, J.; Schenkel, T. Electrically detected magnetic resonance of neutral donors interacting with a two-dimensional electron gas, Phys. Rev. Lett. 2011, 106 (doi: 20760110.1103/PhysRevLett.106.207601).
  108.  Liu, G.; Khlobystov, A. N.; Ardavan, A.; Briggs, G. A. D.; Porfyrakis, K. Photochemical stability of n@c(60) and its pyrrolidine derivatives, Chemical Physics Letters 2011, 508, 187-190 (doi: 10.1016/j.cplett.2011.04.039).
  109.  Lillington, J. E. D.; Lovett, J. E.; Johnson, S.; Roversi, P.; Timmel, C. R.; Lea, S. M. Shigella flexneri spa15 crystal structure verified in solution by double electron electron resonance, Journal of Molecular Biology 2011, 405, 427-435 (doi: 10.1016/j.jmb.2010.10.053).
  110.  Lang, V.; Lo, C. C.; George, R. E.; Lyon, S. A.; Bokor, J.; Schenkel, T.; Ardavan, A.; Morton, J. J. L. Electrically detected magnetic resonance in a w-band microwave cavity, Review of Scientific Instruments 2011, 82 (doi: 03470410.1063/1.3557395).
  111.  Jones, J. A.; Maeda, K.; Steiner, U. E.; Hore, P. J. Reply to comment on 'spin-selective reactions of radical pairs act as quantum measurements', Chemical Physics Letters 2011, 508, 184-185 (doi: 10.1016/j.cplett.2011.04.022).
  112.  Jones, J. A.; Maeda, K.; Hore, P. J. Reaction operators for spin-selective chemical reactions of radical pairs, Chem. Phys. Lett. 2011, 507, 269-273 (doi: 10.1016/j.cplett.2011.03.082).
  113.  Irwin, M.; Kraemer, T.; McGrady, J. E.; Goicoechea, J. M. On the structural and electronic properties of [zn(2)(4,4 '-bipyridine)(mes)(4)](n-) (n=0-2), a homologous series of bimetallic complexes bridged by neutral, anionic, and dianionic 4,4 '-bipyridine, Inorg. Chem. 2011, 50, 5006-5014 (doi: 10.1021/ic200241d).
  114.  Denning, R. G.; Harmer, J.; Green, J. C.; Irwin, M. Covalency in the 4f shell of tris-cyclopentadienyl ytterbium (ybcp3)-a spectroscopic evaluation, Journal of the American Chemical Society 2011, 133, 20644-20660 (doi: 10.1021/ja209311g).
  115.  Brown, R. M.; Tyryshkin, A. M.; Porfyrakis, K.; Gauger, E. M.; Lovett, B. W.; Ardavan, A.; Lyon, S. A.; Briggs, G. A. D.; Morton, J. J. L. Coherent state transfer between an electron and nuclear spin in n-15@c-60, Phys. Rev. Lett. 2011, 106, 110504 (doi: 11050410.1103/PhysRevLett.106.110504).
  116.  Ardavan, A.; Briggs, G. A. D. Quantum control in spintronics, Philosophical Transactions of the Royal Society a-Mathematical Physical and Engineering Sciences 2011, 369, 3229-3248 (doi: 10.1098/rsta.2011.0009).
  117.  Abe, E.; Wu, H.; Ardavan, A.; Morton, J. J. L. Electron spin ensemble strongly coupled to a three-dimensional microwave cavity, Applied Physics Letters 2011, 98 (doi: 25110810.1063/1.3601930).
  118.  Zhou, B.; Goicoechea, J. M. Studies on the reactivity of [ge(9)](4-) towards [fe(cot)(co)(3)]: Synthesis and characterization of [ge(8)fe(co)(3)](3-) and of the anionic organometallic species [fe(cot)(co)(3)](-), Chemistry-a European Journal 2010, 16, 11145-11150 (doi: 10.1002/chem.201090507).
  119.  Zaka, M.; Warner, J. H.; Ito, Y.; Morton, J. J. L.; Rummeli, M. H.; Pichler, T.; Ardavan, A.; Shinohara, H.; Briggs, G. A. D. Exchange interactions of spin-active metallofullerenes in solid-state carbon networks, Physical Review B 2010, 81 (doi: 10.1103/PhysRevB.81.075424).
  120.  Zaka, M.; Ito, Y.; Wang, H. L.; Yan, W. J.; Robertson, A.; Wu, Y. M. A.; Rummeli, M. H.; Staunton, D.; Hashimoto, T.; Morton, J. J. L.; Ardavan, A.; Briggs, G. A. D.; Warner, J. H. Electron paramagnetic resonance investigation of purified catalyst-free single-walled carbon nanotubes, ACS Nano 2010, 4, 7708-7716 (doi: 10.1021/nn102602a).
  121.  Xu, J. H.; Harmer, J.; Li, G. Q.; Chapman, T.; Collier, P.; Longworth, S.; Tsang, S. C. Size dependent oxygen buffering capacity of ceria nanocrystals, Chemical Communications 2010, 46, 1887-1889 (doi: 10.1039/b923780a).
  122.  Wu, H.; George, R. E.; Wesenberg, J. H.; Molmer, K.; Schuster, D. I.; Schoelkopf, R. J.; Itoh, K. M.; Ardavan, A.; Morton, J. J. L.; Briggs, G. A. D. Storage of multiple coherent microwave excitations in an electron spin ensemble, Phys. Rev. Lett. 2010, 105 (doi: 14050310.1103/PhysRevLett.105.140503).
  123.  Simmons, S.; Jones, J. A.; Karlen, S. D.; Ardavan, A.; Morton, J. J. L. Magnetic field sensors using 13-spin cat states, Physical Review A 2010, 82 (doi: 10.1103/PhysRevA.82.022330).
  124.  Schaffry, M.; Filidou, V.; Karlen, S. D.; Gauger, E. M.; Benjamin, S. C.; Anderson, H. L.; Ardavan, A.; Briggs, G. A. D.; Maeda, K.; Henbest, K. B.; Giustino, F.; Morton, J. J. L.; Lovett, B. W. Entangling remote nuclear spins linked by a chromophore, Phys. Rev. Lett. 2010, 104 (doi: 10.1103/PhysRevLett.104.200501).
  125.  Roessler, M. M.; King, M. S.; Robinson, A. J.; Armstrong, F. A.; Harmer, J.; Hirst, J. Direct assignment of epr spectra to structurally defined iron-sulfur clusters in complex i by double electron-electron resonance, Proceedings of the National Academy of Sciences of the United States of America 2010, 107, 1930-1935 (doi: 10.1073/pnas.0908050107).
  126.  Rahman, R.; Tiwari, A.; Dantelle, G.; Morton, J. J. L.; Porfyrakis, K.; Ardavan, A.; Dinse, K.-P.; Briggs, G. A. D. Electron paramagnetic resonance study of ersc2nc80, arXiv:1004.3912 2010, Chemical Physics (physics.chem-ph) (doi: arXiv:1004.3912).
  127.  Puschmann, F. F.; Harmer, J.; Stein, D.; Ruegger, H.; de Bruin, B.; Grutzmacher, H. Electromeric rhodium radical complexes, Angewandte Chemie-International Edition 2010, 49, 385-389 (doi: 10.1002/anie.200903201).
  128.  Neil, S. R. T.; Maeda, K.; Henbest, K. B.; Goez, M.; Hemmens, R.; Timmel, C. R.; Mackenzie, S. R. Cavity enhanced detection methods for probing the dynamics of spin correlated radical pairs in solution, Mol. Phys. 2010, 108, 993-1003 (doi: 10.1080/00268971003614368).
  129.  Maeda, K.; Robinson, A. J.; Henbest, K. B.; Dell, E. J.; Timmel, C. R. Protein surface interactions probed by magnetic field effects on chemical reactions, Journal of the American Chemical Society 2010, 132, 1466-+ (doi: 10.1021/ja908988u).
  130.  Ivanov, K. L.; Petrova, M. V.; Lukzen, N. N.; Maeda, K. Consistent treatment of spin-selective recombination of a radical pair confirms the haberkorn approach, Journal of Physical Chemistry A 2010, 114, 9447-9455 (doi: 10.1021/jp1048265).
  131.  Ito, Y.; Warner, J. H.; Brown, R.; Zaka, M.; Pfeiffer, R.; Aono, T.; Izumi, N.; Okimoto, H.; Morton, J. J. L.; Ardavan, A.; Shinohara, H.; Kuzmany, H.; Peterlik, H.; Briggs, G. A. D. Controlling intermolecular spin interactions of la@c(82) in empty fullerene matrices, Physical Chemistry Chemical Physics 2010, 12, 1618-1623 (doi: 10.1039/b913593f).
  132.  Irwin, M.; Jenkins, R. K.; Denning, M. S.; Kraemer, T.; Grandjean, F.; Long, G. J.; Herchel, R.; McGrady, J. E.; Goicoechea, J. M. Experimental and computational study of the structural and electronic properties of fe(ii)(2,2 '-bipyridine)(mes)(2) and [fe(ii)(2,2 '-bipyridine)(mes)(2)](-), a complex containing a 2,2 '-bipyridyl radical anion, Inorg. Chem. 2010, 49, 6160-6171 (doi: 10.1021/ic100817s).
  133.  Hiney, R. M.; Chaplin, A. B.; Harmer, J.; Green, J. C.; Weller, A. S. Using epr to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [rh-6(pcy3)(6)h-12](+) and [rh-6(pcy3)(6)h-14](+), Dalton Transactions 2010, 39, 1726-1733 (doi: 10.1039/b919209c).
  134.  George, R. E.; Witzel, W.; Riemann, H.; Abrosimov, N. V.; Noetzel, N.; Thewalt, M. L. W.; Morton, J. J. L. Electron spin coherence and electron nuclear double resonance of bi donors in natural si, Phys. Rev. Lett. 2010, 105 (doi: 06760110.1103/PhysRevLett.105.067601).
  135.  Ebner, S.; Jaun, B.; Goenrich, M.; Thauer, R. K.; Harmer, J. Binding of coenzyme b induces a major conformational change in the active site of methyl-coenzyme m reductase, J Am Chem Soc 2010, 132, 567-575 (doi: 10.1021/ja906367h).
  136.  Brown, R. M.; Ito, Y.; Warner, J. H.; Ardavan, A.; Shinohara, H.; Briggs, G. A. D.; Morton, J. J. L. Electron spin coherence in metallofullerenes: Y, sc, and la@c(82), Physical Review B 2010, 82 (doi: 03341010.1103/PhysRevB.82.033410).
  137.  Bell, S. G.; Xu, F.; Johnson, E. O. D.; Forward, I. M.; Bartlam, M.; Rao, Z.; Wong, L.-L. Protein recognition in ferredoxin-p450 electron transfer in the class i cyp199a2 system from rhodopseudomonas palustris, Journal of Biological Inorganic Chemistry 2010, 15, 315-328 (doi: 10.1007/s00775-009-0604-7).
  138.  Bell, S. G.; Tan, A. B. H.; Johnson, E. O. D.; Wong, L.-L. Selective oxidative demethylation of veratric acid to vanillic acid by cyp199a4 from rhodopseudomonas palustris haa2, Molecular Biosystems 2010, 6, 206-214 (doi: 10.1039/b913487e).
  139.  Whitehouse, C. J. C.; Bell, S. G.; Yang, W.; Yorke, J. A.; Blanford, C. F.; Strong, A. J. F.; Morse, E. J.; Bartlam, M.; Rao, Z.; Wong, L.-L. A highly active single-mutation variant of p450(bm3) (cyp102a1), Chembiochem 2009, 10, 1654-1656 (doi: 10.1002/cbic.200900279).
  140.  Wedge, C. J.; Rodgers, C. T.; Norman, S. A.; Baker, N.; Maeda, K.; Henbest, K. B.; Timmel, C. R.; Hore, P. J. Radiofrequency polarization effects in low-field electron paramagnetic resonance, Physical Chemistry Chemical Physics 2009, 11, 6573-6579 (doi: 10.1039/b907915g).
  141.  Smith, C. I.; Miyaoka, H.; Ichikawa, T.; Jones, M. O.; Harmer, J.; Ishida, W.; Edwards, P. P.; Kojima, Y.; Fuji, H. Electron spin resonance investigation of hydrogen absorption in ball-milled graphite, Journal of Physical Chemistry C 2009, 113, 5409-5416 (doi: 10.1021/jp809902r).
  142.  Rodgers, C. T.; Wedge, C. J.; Norman, S. A.; Kukura, P.; Nelson, K.; Baker, N.; Maeda, K.; Henbest, K. B.; Hore, P. J.; Timmel, C. R. Radiofrequency polarization effects in zero-field electron paramagnetic resonance, Physical Chemistry Chemical Physics 2009, 11, 6569-6572 (doi: 10.1039/b906102a).
  143.  Oropeza, F. E.; Harmer, J.; Egdell, R. G.; Palgrave, R. G. A critical evaluation of the mode of incorporation of nitrogen in doped anatase photocatalysts, Phys Chem Chem Phys 2009, 12, 960-969 (doi: 10.1039/b914733k).
  144.  Morton, J. A silicon-based cluster state quantum computer, 2009, Quantum Physics (quant-ph) (doi: ).
  145.  Morley, G. W.; van Tol, J.; Ardavan, A.; Porfyrakis, K.; Zhang, J.; Briggs, G. A. D. Efficient dynamic nuclear polarization at high magnetic fields (vol 98, 220501, 2007), Phys. Rev. Lett. 2009, 103 (doi: 19990210.1103/PhysRevLett.103.199902).
  146.  Lukey, M. J.; Parkin, A.; Roessler, M. M.; Murphy, B. J.; Harmer, J.; Palmer, T.; Sargent, F.; Armstrong, F. A. How escherichia coli is equipped to oxidize hydrogen under different redox conditions, J Biol Chem 2009, 285, 3928-3938 (doi: 10.1074/jbc.M109.067751).
  147.  Lovett, J. E.; Hoffmann, M.; Cnossen, A.; Shutter, A. T. J.; Hogben, H. J.; Warren, J. E.; Pascu, S. I.; Kay, C. W. M.; Timmel, C. R.; Anderson, H. L. Probing flexibility in porphyrin-based molecular wires using double electron electron resonance, Journal of the American Chemical Society 2009, 131, 13852-13859 (doi: 10.1021/ja905796z).
  148.  Lovett, J. E.; Bowen, A. M.; Timmel, C. R.; Jones, M. W.; Dilworth, J. R.; Caprotti, D.; Bell, S. G.; Wong, L. L.; Harmer, J. Structural information from orientationally selective deer spectroscopy, Physical Chemistry Chemical Physics 2009, 11, 6840-6848 (doi: 10.1039/b907010a).
  149.  Jones, J. A.; Karlen, S. D.; Fitzsimons, J.; Ardavan, A.; Benjamin, S. C.; Briggs, G. A. D.; Morton, J. J. L. Magnetic field sensing beyond the standard quantum limit using 10-spin noon states, Science 2009, 324, 1166-1168 (doi: 10.1126/science.1170730).
  150.  Jones, J. A. Composite pulses in nmr quantum computation, J. Ind. Inst. Sci. 2009, 89, 303-308 (doi: arXiv:0906.4719v1).
  151.  Gore-Randall, E.; Irwin, M.; Denning, M. S.; Goicoechea, J. M. Synthesis and characterization of alkali-metal salts of 2,2 '- and 2,4 '-bipyridyl radicals and dianions, Inorg. Chem. 2009, 48, 8304-8316 (doi: 10.1021/ic9009459).
  152.  Ebner, S.; Jaun, B.; Goenrich, M.; Thauer, R. K.; Harmer, J. Binding of coenzyme b induces a major conformational change in the active site of methyl-coenzyme m reductase, J Am Chem Soc 2009, 132, 567-575 (doi: 10.1021/ja906367h).
  153.  Chuan, H.; Bell, S. G.; Wen, Y.; Hui, W.; Yiming, H.; Xin, L.; Weihong, Z.; Bartlamac, M.; Luet-Lok, W. Purification, crystallization and preliminary x-ray analysis of cytochrome p450 219a1 from novosphingobium aromaticivorans dsm 12444, Acta Crystallographica, Section F (Structural Biology and Crystallization Communications) 2009, F65 (doi: 10.1107/s1744309109005648).
  154.  Barry, E. R.; Lovett, J. E.; Costa, A.; Lea, S. M.; Bell, S. D. Intersubunit allosteric communication mediated by a conserved loop in the mcm helicase, Proceedings of the National Academy of Sciences of the United States of America 2009, 106, 1051-1056 (doi: 10.1073/pnas.0809192106).
  155.  Ardavan, A.; Blundell, S. J. Storing quantum information in chemically engineered nanoscale magnets, Journal of Materials Chemistry 2009, 19, 1754-1760 (doi: 10.1039/b809525f).
  156.  Zhang, J.; Porfyrakis, K.; Morton, J. J. L.; Sambrook, M. R.; Harmer, J.; Xiao, L.; Ardavan, A.; Briggs, G. A. D. Photoisomerization of a fullerene dimer, Journal of Physical Chemistry C 2008, 112, 2802-2804 (doi: 10.1021/jp711861z).
  157.  Whitehouse, C. J. C.; Bell, S. G.; Wong, L.-L. Desaturation of alkylbenzenes by cytochrome p450(bm3) (cyp102a1), Chemistry-a European Journal 2008, 14, 10905-10908 (doi: 10.1002/chem.200801927).
  158.  Whitehouse, C. J. C.; Bell, S. G.; Tufton, H. G.; Kenny, R. J. P.; Ogilvie, L. C. I.; Wong, L.-L. Evolved cyp102a1 (p450(bm3)) variants oxidise a range of non-natural substrates and offer new selectivity options, Chemical Communications 2008, 966-968 (doi: 10.1039/b718124h).
  159.  Morton, J. J. L.; Tyryshkin, A. M.; Brown, R. M.; Shankar, S.; Lovett, B. W.; Ardavan, A.; Schenkel, T.; Haller, E. E.; Ager, J. W.; Lyon, S. A. Solid-state quantum memory using the p-31 nuclear spin, Nature 2008, 455, 1085-1088 (doi: 10.1038/nature07295).
  160.  Morton, J. J. L.; Tiwari, A.; Dantelle, G.; Porfyrakis, K.; Ardavan, A.; Briggs, G. A. D. Switchable ersc2n rotor within a c-80 fullerene cage: An electron paramagnetic resonance and photoluminescence excitation study, Phys. Rev. Lett. 2008, 101, 4 (doi: 01300210.1103/PhysRevLett.101.013002).
  161.  Hinderberger, D.; Ebner, S.; Mayr, S.; Jaun, B.; Reiher, M.; Goenrich, M.; Thauer, R. K.; Harmer, J. Coordination and binding geometry of methyl-coenzyme m in the red1m state of methyl-coenzyme m reductase, Journal of Biological Inorganic Chemistry 2008, 13, 1275-1289 (doi: 10.1007/s00775-008-0417-0).
  162. Maeda, K.; Henbest, K.B.; Cintolesi, K.; Kuprov, I.; Rodgers, C.T.; Liddell, P.A.; Gust, D.; Timmel C.R.; Hore, P.J. Chemical Compass Model of Avian Magnetoreception, Nature 2008, 453, 387 (doi:10.1038/nature06834).
  163.  Henbest, K. B.; Maeda, K.; Hore, P. J.; Joshi, M.; Bacher, A.; Bittl, R.; Weber, S.; Timmel, C. R.; Schleicher, E. Magnetic-field effect on the photoactivation reaction of escherichia coli DNA photolyase, Proceedings of the National Academy of Sciences of the United States of America 2008, 105, 14395-14399 (doi: 10.1073/pnas.0803620105).
  164.  Harmer, J.; Finazzo, C.; Piskorski, R.; Ebner, S.; Duin, E. C.; Goenrich, M.; Thauer, R. K.; Reiher, M.; Schweiger, A.; Hinderberger, D.; Jaun, B. A nickel hydride complex in the active site of methyl-coenzyme m reductase: Implications for the catalytic cycle, Journal of the American Chemical Society 2008, 130, 10907-10920 (doi: 10.1021/ja710949e).
  165.  Guo, D.; Xu, F.; Bell, S. G.; Pang, X.; Bartlam, M.; Wong, L.-L. Purification, crystallization and preliminary crystallographic analysis of cyp 195a2, a p450 enzyme from rhodopseudomonas palustris, Protein and peptide letters 2008, 15, 423-426 (doi: 10.2174/092986608784246470).
  166.  Godinho, K. G.; Watson, G. W.; Walsh, A.; Green, A. J. H.; Payne, D. J.; Harmer, J.; Egdell, R. G. A comparative study of the electronic structures of srcu2o2 and pbcu2o2 by density functional theory, high resolution x-ray photoemission and electron paramagnetic resonance spectroscopy, Journal of Materials Chemistry 2008, 18, 2798-2806 (doi: 10.1039/b719364e).
  167.  Donati, N.; Stein, D.; Buttner, T.; Schonberg, H.; Harmer, J.; Anadaram, S.; Grutzmacher, H. Rhodium and iridium amino, amido, and aminyl radical complexes, Eur. J. Inorg. Chem. 2008, 4691-4703 (doi: 10.1002/ejic.200800702).
  168.  Denning, M. S.; Irwin, M.; Goicoechea, J. M. Synthesis and characterization of the 4,4 '-bipyridyl dianion and radical monoanion. A structural study, Inorg. Chem. 2008, 47, 6118-6120 (doi: 10.1021/ic800726p).
  169.  Bell, S. G.; Xu, F.; Forward, I.; Bartlam, M.; Rao, Z.; Wong, L.-L. Crystal structure of cyp199a2, a para-substituted benzoic acid oxidizing cytochrome p450 from rhodopseudomonas palustris, Journal of Molecular Biology 2008, 383, 561-574 (doi: 10.1016/j.jmb.2008.08.033).
  170.  Banham, J. E.; Baker, C. M.; Ceola, S.; Day, I. J.; Grant, G. H.; Groenen, E. J. J.; Rodgers, C. T.; Jeschke, G.; Timmel, C. R. Distance measurements in the borderline region of applicability of cw epr and deer: A model study on a homologous series of spin-labelled peptides, J. Magn. Reson. 2008, 191, 202-218 (doi: 10.1016/j.jmr.2007.11.023).
  171.  Morton, J. J. L.; Tyryshkin, A. M.; Ardavan, A.; Porfyrakis, K.; Lyon, S. A.; Briggs, G. A. D. Environmental effects on electron spin relaxation in n@c-60, Physical Review B 2007, 76 (doi: 08541810.1103/PhysRevB.76.085418).
  172.  Eelkema, R.; Maeda, K.; Odell, B.; Anderson, H. L. Radical cation stabilization in a cucurbituril oligoaniline rotaxane, Journal of the American Chemical Society 2007, 129, 12384-12385 (doi: 10.1021/ja074997i).
  173.  Bell, S. G.; Wong, L.-L. P450 enzymes from the bacterium novosphingobium aromaticivorans, Biochemical and Biophysical Research Communications 2007, 360, 666-672 (doi: 10.1016/j.bbrc.2007.06.119).
  174.  Banham, J. E.; Jeschke, G.; Timmel, C. R. Evidence from epr that nitroxide spin labels attached to human hemoglobin alter their conformation upon freezing, Mol. Phys. 2007, 105, 2041-2047 (doi: 10.1080/00268970701579501).
  175.  Ardavan, A.; Rival, O.; Morton, J. J. L.; Blundell, S. J.; Tyryshkin, A. M.; Timco, G. A.; Winpenny, R. E. P. Will spin-relaxation times in molecular magnets permit quantum information processing?, Phys. Rev. Lett. 2007, 98, Art. No. 057201 (doi: 10.1103/PhysRevLett.98.057201).